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Magnetocaloric properties of Ni49.9Mn19.6Cu5.7Ga24.8 single crystal processed by Bridgman method with stationary crucible

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Abstract Bridgman method with stationary crucible was used to grow NiMnCuGa single crystal. Microstructure observations, as well as XRD pattern, revealed a presence of martensitic structure at room temperature. Crystal… Click to show full abstract

Abstract Bridgman method with stationary crucible was used to grow NiMnCuGa single crystal. Microstructure observations, as well as XRD pattern, revealed a presence of martensitic structure at room temperature. Crystal structure was determined as a non-modulated tetragonal martensite. The phase transition occurred at 296 K and 290 K on heating and cooling, respectively. Magnetic entropy change (ΔS M ) reached a peak value of −9.86 J/kgK at the field of 1520 kA/m. Refrigerant capacity (RC), calculated at FWHM of the ΔS M peak, reached a value of 28.5 J/kg. Directly measured adiabatic temperature change (ΔT ad ) spread over 51 K range and its maximum value reached 0.23 K at 1520 kA/m field.

Keywords: stationary crucible; method stationary; single crystal; bridgman method

Journal Title: Materials Letters
Year Published: 2018

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