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Molten salt synthesis, characterization and luminescence of Tb3−xCexAl5O12 (TAG:Ce) phosphors

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Abstract The Tb3−xCexAl5O12 (TAG:Ce) phosphors with various cerium doped concentrations were successfully prepared via molten salt (MS) synthesis method using the eutectic mixtures of NaNO2-KNO2 as the flux. Tb3Al5O12 phase… Click to show full abstract

Abstract The Tb3−xCexAl5O12 (TAG:Ce) phosphors with various cerium doped concentrations were successfully prepared via molten salt (MS) synthesis method using the eutectic mixtures of NaNO2-KNO2 as the flux. Tb3Al5O12 phase can be formed at a temperature as low as 450 °C, but the as-prepared TAG:Ce phosphor with a 250 nm average particle size do not have noticeable emission and excitation spectra. However, after being annealed in a reducing atmosphere at 1100 °C, the phosphor was found to have the same particle size, and more importantly, stronger emission and excitation spectra as well. The results show that the modified MS method provides a feasible approach to produce TAG:Ce phosphor for optoelectronic applications.

Keywords: tb3 xcexal5o12; xcexal5o12 tag; salt synthesis; molten salt; tag phosphors; tag

Journal Title: Materials Letters
Year Published: 2018

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