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From Sm3+:La2O3-ZnO-Na2O-TeO2 glasses to transparent glass ceramics containing ZnTeO3 and La2Te4O11 nanocrystals – Influence of the heat treatment on crystal growth and fluorescence properties

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Abstract The paper presents the synthesis and spectroscopic properties of Sm3+-doped transparent TeO2-based glass ceramics containing ZnTeO3 and La2Te4O11 nanocrystals. The impact of heat treatment is presented and discussed. X-ray… Click to show full abstract

Abstract The paper presents the synthesis and spectroscopic properties of Sm3+-doped transparent TeO2-based glass ceramics containing ZnTeO3 and La2Te4O11 nanocrystals. The impact of heat treatment is presented and discussed. X-ray diffraction and transmission electron microscope results demonstrate that nanocrystals are precipitated homogenously among the glass matrix. Excitation in the 6P3/2 bands of Sm3+ produces a strong orange and red emission from the 4G5/2 level. The results show noticeable differences between glass precursor, bulk and nanocrystalline Sm3+:La2Te4O11 in luminescence experimental data.

Keywords: znteo3 la2te4o11; la2te4o11 nanocrystals; glass; glass ceramics; containing znteo3; ceramics containing

Journal Title: Materials Letters
Year Published: 2018

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