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In-situ synthesis of zeolites by geopolymerization of biomass fly ash and metakaolin

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Abstract This study aims to evaluate the in-situ synthesis of zeolites through geopolymerization of biomass fly ash wastes at low temperature in a hermetic container. The raw materials were activated… Click to show full abstract

Abstract This study aims to evaluate the in-situ synthesis of zeolites through geopolymerization of biomass fly ash wastes at low temperature in a hermetic container. The raw materials were activated using a mixture of sodium silicate and sodium hydroxide, and then the specimens cured at 60 °C to obtain zeolite-containing geopolymers. Hydrogen peroxide (H2O2) was used as a porogenic agent. X-ray diffractograms showed the presence of faujasite zeolites regardless of the added H2O2 content. P zeolite was formed without porogenic agent addition, resulting in increase in the surface area (56.35 m2/g) in comparison with samples cured in room conditions (40.69 m2/g). The identified zeolites and the mechanical strength (up to ∼10 MPa) suggest applications as separation membranes or filters.

Keywords: zeolites geopolymerization; synthesis zeolites; situ synthesis; biomass fly; fly ash; geopolymerization biomass

Journal Title: Materials Letters
Year Published: 2019

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