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Fe(III) doped ZnO nano-assembly as a potential heterogeneous nano-catalyst for the production of biodiesel

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Abstract Bimetallic Fe(III) doped ZnO (FZO) nanoparticles (NPs) were synthesized to be utilized as heterogeneous nano-catalysts. The synthesized NPs were characterized using various physical techniques. Average particle size and surface… Click to show full abstract

Abstract Bimetallic Fe(III) doped ZnO (FZO) nanoparticles (NPs) were synthesized to be utilized as heterogeneous nano-catalysts. The synthesized NPs were characterized using various physical techniques. Average particle size and surface area of NPs were found to be 76.24 ± 17 nm, and 12.39 m2 g−1, respectively. Designed nano-catalyst was found to be soft ferromagnetic in nature, with 1.32 ± 0.2 emu g−1 magnetization and 75.52 ± 2 Oe coercivity. FZO NPs indicated efficient transesterification reaction using soybean oil and methanol. The biodiesel was produced within 3 h, and was found to be remarkably rich in C18 methyl esters. The heterogeneous catalyst was recovered around 90 ± 2% and exhibited excellent transesterification ability upon its reuse. Therefore, the present study postulates the designed bimetallic FZO NPs as a potential heterogonous nano-catalyst for the efficient production of biodiesel.

Keywords: biodiesel; nano; catalyst; doped zno; iii doped; nano catalyst

Journal Title: Materials Letters
Year Published: 2019

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