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Abstract Titanium-containing zeolitic catalysts show high activity and selectivity in numerous environmentally-friendly oxidation reactions. However, the small micropores show severe restrictions for the oxidation of large organic reactants. Here, Ti-SFN… Click to show full abstract
Abstract Titanium-containing zeolitic catalysts show high activity and selectivity in numerous environmentally-friendly oxidation reactions. However, the small micropores show severe restrictions for the oxidation of large organic reactants. Here, Ti-SFN zeolite with 14-ring extra-large-pores (6.2 × 8.5 A) was firstly synthesized by a chemical vapor deposition method and proved to have superior catalytic performance for bulker molecular oxidation using hydrogen peroxide as an oxidant compared to 10-ring TS-1 and 14-ring Ti-CIT-5 zeolites.
Journal Title: Materials Letters
Year Published: 2019
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