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BiVO4-nanorod-decorated rutile/anatase TiO2 nanofibers with enhanced photoelectrochemical performance

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Abstract Bismuth vanadate (BiVO4) nanorods (NRs)/bi-phase TiO2 hierarchical nanofibers have been successfully synthesized by electrospinning combined with hydrothermal process. Experimental results demonstrate that BiVO4/bi-phase TiO2 hierarchical nanofibers present the multilevel… Click to show full abstract

Abstract Bismuth vanadate (BiVO4) nanorods (NRs)/bi-phase TiO2 hierarchical nanofibers have been successfully synthesized by electrospinning combined with hydrothermal process. Experimental results demonstrate that BiVO4/bi-phase TiO2 hierarchical nanofibers present the multilevel structures composed of BiVO4 NRs inlaid into TiO2 nanofibers. The as-prepared samples have the lower electron-hole recombination rates and higher transmission efficiency compared with pure BiVO4 NRs and bi-phase TiO2 nanofibers. The photocatalytic activities of the as-prepared samples are evaluated by photodegrading 4-nitrophenol (4-NP) solution, and the photocatalytic degradation rate of the BiVO4/bi-phase TiO2 hierarchical nanofibers reaches as high as 95.7% under simulated sunlight irradiation. The high photoelectrocatalytic properties of BiVO4/bi-phase TiO2 hierarchical nanofibers could be attributed to the successful establishment of BiVO4 and TiO2 heterojunctions.

Keywords: tio2; tio2 hierarchical; phase tio2; bivo4; tio2 nanofibers

Journal Title: Materials Letters
Year Published: 2020

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