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Ketoprofen degradation by surface reactive species on TiO2, AgxOy/MoxOy/catalysts

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Abstract In this research, the surface functionalization of TiO2 by silver and molybdenum species was used for the degradation and mineralization of ketoprofen. The catalyst was synthesized by a controlled… Click to show full abstract

Abstract In this research, the surface functionalization of TiO2 by silver and molybdenum species was used for the degradation and mineralization of ketoprofen. The catalyst was synthesized by a controlled wet impregnation method and characterized by several techniques; mineralization and degradation were quantified with HPLC and TOC (Total Organic Carbon) achieving more than 40 and 60 % according to the pH. The higher removal using bimetallic synthesized catalyst compared with P25 TiO2 is due to the surface species, Ag, Ag+, MoO3, and Mo5+ that decrease the bandgap energy that inhibit the recombination of photoelectrons and charge separation. The as-synthetized nanocomposites stand as an alternative for the non-steroidal-anti-inflammatory drug commonly found in wastewater.

Keywords: ketoprofen degradation; surface reactive; reactive species; surface; degradation surface; degradation

Journal Title: Materials Letters
Year Published: 2021

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