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High Utilization Rate Thermal Batteries Using PbCl2 as a Cathode Material

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Abstract In view of the shortcomings of low utilization rate of disulfide cathode for thermal battery, chloride has been developed as a candidate material for thermal battery cathode. In this… Click to show full abstract

Abstract In view of the shortcomings of low utilization rate of disulfide cathode for thermal battery, chloride has been developed as a candidate material for thermal battery cathode. In this case, PbCl2 was tried to be used as a cathode material for thermal batteries and tested the electrical properties of single battery. The discharge specific capacity can reach 168 mAh/g at 450℃ and 0.5 C current, the voltage plateau reaches 1.8 V, and the active material utilization rate is as high as 87.5% when the cut-off voltage is 0.5 V. The only discharge platform and high utilization rate enable PbCl2 to be used as the active material for thermal batteries, which also provides a new direction for the chloride cathode active material for thermal batteries.

Keywords: thermal batteries; utilization rate; material; cathode

Journal Title: Materials Letters
Year Published: 2021

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