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Surfactant Controlled Metal Oxide Shell Layer Deposition for Enhanced Photocatalytic Solar Hydrogen Generation: CdSe/TiO2 Nanocomposite a Case Study

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Abstract The present work demonstrates the effect of cationic, anionic and nonionic surfactants on synthesizing nanoscale thin TiO2 shell layer deposited on to pre-synthesized CdSe capsule-like nanoparticles. We benchmark a… Click to show full abstract

Abstract The present work demonstrates the effect of cationic, anionic and nonionic surfactants on synthesizing nanoscale thin TiO2 shell layer deposited on to pre-synthesized CdSe capsule-like nanoparticles. We benchmark a suitable surfactant for synthesizing homogenous, controlled TiO2 post-deposition onto host 1-D CdSe surface without any complex research tools. Also, we examine the inter-dependence material property and photocatalytic performance in solar hydrogen generation. The generic synthesis of surfactant controlled nanoscale deposition route can transfer to a wide range of semiconductor materials where the surface functional property plays a crucial role.

Keywords: hydrogen generation; cdse; tio2; solar hydrogen; deposition; shell layer

Journal Title: Materials Letters
Year Published: 2021

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