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Selective phosphorus doping of polycrystalline silicon on glass using self-assembled monolayer doping (MLD) and flash anneal

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Abstract We report doping of thin (~60 nm) amorphous silicon (a-Si) on glass substrate to form n + polycrystalline silicon on glass in selective regions using Monolayer doping (MLD) via Flash Lamp Annealing… Click to show full abstract

Abstract We report doping of thin (~60 nm) amorphous silicon (a-Si) on glass substrate to form n + polycrystalline silicon on glass in selective regions using Monolayer doping (MLD) via Flash Lamp Annealing (FLA). The phosphorus monolayer was formed on the exposed regions of SiO2 patterned a-Si, through functionalization with chemically bound Diethyl vinylphosphonate (DVP) dopant molecules. The samples were capped with SiO2 and annealed using a single xenon flash pulse (5.0 J/cm2, 250 μs) to simultaneously crystallize a-Si, incorporate and activate phosphorus dopants. SIMS results show an average concentration of 8x1019 cm−3 in the 60 nm of thin silicon on glass. Electrical results show a resistivity of ~6.60x10−2 Ω.cm in doped regions. N-channel field effect transistor devices are successfully demonstrated using this MLD-FLA technique.

Keywords: phosphorus; silicon glass; monolayer; silicon; polycrystalline silicon

Journal Title: Materials Letters
Year Published: 2021

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