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Exploring the influence of designer surfactant hydrophobicity in key C C/C N bond forming reactions

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Abstract Designer micellar medium was explored for the transformation of diverse anilines to the corresponding densely substituted biologically relevant skatole derivatives in an aqueous medium via 5-exo-trig cyclization reaction. The… Click to show full abstract

Abstract Designer micellar medium was explored for the transformation of diverse anilines to the corresponding densely substituted biologically relevant skatole derivatives in an aqueous medium via 5-exo-trig cyclization reaction. The scope of the reaction was extended to intermolecular Csp2-Csp2 and Csp2-N bond forming reactions in water. Systematic investigations revealed that altering hydrophobicity of surfactant influences the yield of both C C and C N bond forming reactions in water.

Keywords: designer; bond forming; hydrophobicity; exploring influence; forming reactions

Journal Title: Molecular Catalysis
Year Published: 2019

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