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Hexadecane hydrocracking for production of jet fuels from renewable diesel over proton and metal modified H-Beta zeolites

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Abstract Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods.… Click to show full abstract

Abstract Hydrocracking of hexadecane to produce jet fuel components was investigated over proton and metal modified Beta zeolites with different acidity. They were characterized by a range of physico-chemical methods. The initial catalyst screening was performed at 210 °C under 40 bar hydrogen showing that the most promising catalysts were 2.5 wt% Pt-H-Beta-25 and 2.5 wt% Ru-H-Beta-300, which were also tested at 240 °C under 45 bar hydrogen. The results revealed that the yield of jet fuel components was maximally 27% over 2.5 wt% Pt-H-Beta-25. This catalyst gave, however, only 55% mass balance closure to the liquid phase products, while a mildly acidic 2.5 wt% Ru-H-Beta-300 afforded 24% yield of the jet fuel components and 89% liquid mass balance closure.

Keywords: metal modified; proton metal; modified beta; beta; beta zeolites; jet

Journal Title: Molecular Catalysis
Year Published: 2019

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