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Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one… Click to show full abstract
Zirconocene obtained from 6,6-dimethylfulvene ‘dimer’, being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of α-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.
Keywords:
zirconocene;
catalytic oligomerization;
olefins presence;
dimethylfulvene dimer;
catalyst;
oligomerization olefins
Journal Title: Mendeleev Communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Mendeleev Communications
Year Published: 2017
Link to full text (if available)
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recommendations!