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A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)- 1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane-… Click to show full abstract
A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)- 1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane- 1,2,3-trione 2-oxime has been determined by X-ray crystallography.
Keywords:
polyfluoroalkyl propane;
propane trione;
trione;
polyfluoroalkyl;
trione oximes;
synthesis
Journal Title: Mendeleev Communications
Year Published: 2017
Link to full text (if available)
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Journal Title: Mendeleev Communications
Year Published: 2017
Link to full text (if available)
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recommendations!