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Synthesis of natural phaeosphaeride A and semi-natural phaeosphaeride B derivatives

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6-O-Acylated phaeosphaeride A and phaeosphaeride B in reaction with secondary cyclic amines undergo stereospecific replacement of acyloxy group by pharmacophoric amino moiety. In case of chloroacetoxy derivative, chlorine displacement by… Click to show full abstract

6-O-Acylated phaeosphaeride A and phaeosphaeride B in reaction with secondary cyclic amines undergo stereospecific replacement of acyloxy group by pharmacophoric amino moiety. In case of chloroacetoxy derivative, chlorine displacement by such amines proceeds in the presence of triethylamine.

Keywords: semi natural; phaeosphaeride; phaeosphaeride semi; synthesis natural; natural phaeosphaeride; phaeosphaeride derivatives

Journal Title: Mendeleev Communications
Year Published: 2017

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