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One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions

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A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)2/PCy3 system in the presence of CsF is suitable for substrates bearing functional groups not… Click to show full abstract

A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)2/PCy3 system in the presence of CsF is suitable for substrates bearing functional groups not tolerant to lithium-, magnesium-, zincorganic reagents and strong bases.

Keywords: pot two; step stannylation; two step; one pot; aryl; solvent free

Journal Title: Mendeleev Communications
Year Published: 2018

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