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Unsymmetrical donor–acceptor oligothiophenes end-capped with triphenylamine and phenyldicyanovinyl units

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Highly stable unsymmetrical donor–acceptor oligothiophenes equipped with terminal electron-donating triphenylamine and an electron-withdrawing phenyldicyanovinyl groups have been synthesized. An influence of the length of conjugated oligothiophene π-spacer between the donor… Click to show full abstract

Highly stable unsymmetrical donor–acceptor oligothiophenes equipped with terminal electron-donating triphenylamine and an electron-withdrawing phenyldicyanovinyl groups have been synthesized. An influence of the length of conjugated oligothiophene π-spacer between the donor and acceptor blocks on solubility, thermal, optical and electrochemical properties of such compounds has been revealed.

Keywords: oligothiophenes end; unsymmetrical donor; acceptor oligothiophenes; donor acceptor; donor

Journal Title: Mendeleev Communications
Year Published: 2018

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