A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate… Click to show full abstract
A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate a photochemical version of this interaction resulting in the formation of both 1,1-dichloro-1-silacyclopent-3-ene and 1,1-dichloro-2-vinylsilirane in contrast to the thermal reaction giving only the first of these products.
Keywords:
dichloro vinyl;
vinyl silacyclopropane;
formation;
reaction;
formation dichloro
Journal Title: Mendeleev Communications
Year Published: 2018
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Journal Title: Mendeleev Communications
Year Published: 2018
Link to full text (if available)
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recommendations!