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New olefin metathesis catalysts with fluorinated unsymmetrical imidazole-based ligands

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New olefin metathesis catalysts, unsaturated analogues of the Grubbs II and Hoveyda–Grubbs II ones, bearing bulky (alkoxy)hexafluoroisopropyl groups in one of the aryl substituent of NHC ligand provide high conversions… Click to show full abstract

New olefin metathesis catalysts, unsaturated analogues of the Grubbs II and Hoveyda–Grubbs II ones, bearing bulky (alkoxy)hexafluoroisopropyl groups in one of the aryl substituent of NHC ligand provide high conversions in model ring closing metathesis of diallyl- and allylmethallylmalonates.

Keywords: olefin metathesis; fluorinated unsymmetrical; catalysts fluorinated; new olefin; metathesis catalysts; metathesis

Journal Title: Mendeleev Communications
Year Published: 2018

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