Photo by joshuafernandez from unsplash
The new complex [Cu2(H2L)Cl3] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of… Click to show full abstract
The new complex [Cu2(H2L)Cl3] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of −193 cm−1 that is extremely high for such type of complexes. The quantum chemical calculation of 2J value has perfectly matched an experiment.
Keywords:
based methyl;
pyrimidin hydrazono;
methyl bis;
dimethyl pyrimidin;
bis dimethyl;
methyl
Journal Title: Mendeleev Communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Mendeleev Communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!