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Trans-etherification of catechol-type benzylic ether with diols as a route to new sterically hindered bis-catechols

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The trans-etherification of 4,6-di-tert-butyl-2,3-dihydroxybenzyl methyl ether with α,ω-alkanediols under mild conditions (CHCl3, 65 °C) leads to new sterically hindered biscatechols in high yields. The molecular structures of three of them was… Click to show full abstract

The trans-etherification of 4,6-di-tert-butyl-2,3-dihydroxybenzyl methyl ether with α,ω-alkanediols under mild conditions (CHCl3, 65 °C) leads to new sterically hindered biscatechols in high yields. The molecular structures of three of them was determined by single-crystal X-ray diffraction.

Keywords: ether; trans etherification; new sterically; catechol type; etherification catechol; sterically hindered

Journal Title: Mendeleev Communications
Year Published: 2019

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