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Diimidazo[4,5-b:4′,5′-e]pyridine: synthesis and nucleophilic aromatic substitution reaction

1,7-Dihydrodiimidazo[4,5-b:4′,5′-e]pyridine obtained by reductive heterocyclization was N-arylated with 4-fluoronitrobenzene to form two regioisomers in 7 : 3 ratio. This N-arylation is considered as a model reaction for the polymer synthesis. Click to show full abstract

1,7-Dihydrodiimidazo[4,5-b:4′,5′-e]pyridine obtained by reductive heterocyclization was N-arylated with 4-fluoronitrobenzene to form two regioisomers in 7 : 3 ratio. This N-arylation is considered as a model reaction for the polymer synthesis.

Keywords: nucleophilic aromatic; diimidazo pyridine; synthesis; synthesis nucleophilic; reaction; pyridine synthesis

Journal Title: Mendeleev Communications
Year Published: 2019

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