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Stability of nickel bis(dicarbollide) complexes

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Reactions of nickel( iv ) bis(dicarbollide) with 2,2′-bipyridine or 1,10-phenanthroline in ethanol result in destruction of the metallacarborane cage with formation of the parent and 3-ethoxy substituted nido-carboranes. Click to show full abstract

Reactions of nickel( iv ) bis(dicarbollide) with 2,2′-bipyridine or 1,10-phenanthroline in ethanol result in destruction of the metallacarborane cage with formation of the parent and 3-ethoxy substituted nido-carboranes.

Keywords: stability nickel; nickel bis; bis dicarbollide; dicarbollide complexes

Journal Title: Mendeleev Communications
Year Published: 2019

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