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New spiro-linked indolinone pyrrolidine selenoxoimidazolones

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New 2-selenoxodispiro[imidazolidine-4,3′-pyrrolidine-4′,3″-indoline]-2″,5-dione system was accessed by addition of azomethine ylide at the double bond of (Z)-(2-oxoindolin-3-ylidene)-2-selenoxoimidazolidin-4-one derivatives. The latter were stereoselectively obtained in two steps from ethyl isoselenocyanatoacetate and isatins. Click to show full abstract

New 2-selenoxodispiro[imidazolidine-4,3′-pyrrolidine-4′,3″-indoline]-2″,5-dione system was accessed by addition of azomethine ylide at the double bond of (Z)-(2-oxoindolin-3-ylidene)-2-selenoxoimidazolidin-4-one derivatives. The latter were stereoselectively obtained in two steps from ethyl isoselenocyanatoacetate and isatins.

Keywords: pyrrolidine selenoxoimidazolones; linked indolinone; indolinone pyrrolidine; pyrrolidine; new spiro; spiro linked

Journal Title: Mendeleev Communications
Year Published: 2020

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