Abstract The ability of aluminium-phosphate-sulfate (APS) phases to preferentially sorb lead and its radionuclides, particularly 210Pb, from metallurgical processing streams has been recently recognised empirically. This suggests that APS minerals… Click to show full abstract
Abstract The ability of aluminium-phosphate-sulfate (APS) phases to preferentially sorb lead and its radionuclides, particularly 210Pb, from metallurgical processing streams has been recently recognised empirically. This suggests that APS minerals may be suitable for the removal of lead from environmental and anthropogenic processes. We investigated the Pb sorption capabilities of APS with different Ca:Sr and SO4:PO4 ratios over a range of aqueous Pb concentrations (10–1000 ppm) and pH (1.5–5.5) typical of metallurgical processes and acid drainage conditions. Through a combination of characterization techniques including electron probe microanalysis, (laser ablation-) inductively coupled plasma mass spectrometry and X-ray absorption spectroscopy, we confirm the rapid (
               
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