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Abstract Errors are discovered in the authors' calculated excess enthalpies based on the Buchowski-Ksiazcyak λh equation. The authors inadvertently subtracted the solute's enthalpy of fusion from the product universal gas… Click to show full abstract
Abstract Errors are discovered in the authors' calculated excess enthalpies based on the Buchowski-Ksiazcyak λh equation. The authors inadvertently subtracted the solute's enthalpy of fusion from the product universal gas constant (in Joules/(mole K)) times Buchowski-Ksiazcyak h parameter, without changing the units of solute's enthalpy of fusion to Joules/mole. As a result all of the 81 excess enthalpies given in Table 8 of the published paper by Huang and coworkers are in error.
Keywords:
thermodynamic parameters;
correlation solubility;
comments determination;
solubility thermodynamic;
determination correlation;
parameters tetrahydroxystilbene
Journal Title: Journal of Molecular Liquids
Year Published: 2018
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Journal Title: Journal of Molecular Liquids
Year Published: 2018
Link to full text (if available)
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recommendations!