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Inhibition action of triazolyl blue tetrazolium bromide on cold rolled steel corrosion in three chlorinated acetic acids

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Abstract The inhibition effect of triazolyl blue tetrazolium bromide (TBTB) on cold rolled steel (CRS) in three chlorinated acetic acids of monochloroacetic acid (ClCH2COOH), dichloroacetic acid (Cl2CHCOOH) and trichloroacetic acid… Click to show full abstract

Abstract The inhibition effect of triazolyl blue tetrazolium bromide (TBTB) on cold rolled steel (CRS) in three chlorinated acetic acids of monochloroacetic acid (ClCH2COOH), dichloroacetic acid (Cl2CHCOOH) and trichloroacetic acid (Cl3CCOOH) was studied by weight loss, potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) methods. Meanwhile, the adsorption mechanism of TBT+ (organic part of TBTB) was theoretically investigated by quantum chemical calculation and molecular dynamics (MD) simulations. The results show that TBTB acts as a good inhibitor, and inhibition efficiency in three chlorinated acetic acids follows the order: ClCH2COOH

Keywords: acetic acids; three chlorinated; triazolyl blue; blue tetrazolium; inhibition; chlorinated acetic

Journal Title: Journal of Molecular Liquids
Year Published: 2019

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