Abstract A series of Co(II), Ni(II) and Cu(II) complexes were synthesized with N′1,N′2‑bis(3‑hydroxy‑5,5‑dimethylcyclohex‑2‑en‑1‑ylidene)oxalohydrazide (H4DOX). The geometry of isolated solid compounds was discussed by various spectroscopic methods. The optimized structures of… Click to show full abstract
Abstract A series of Co(II), Ni(II) and Cu(II) complexes were synthesized with N′1,N′2‑bis(3‑hydroxy‑5,5‑dimethylcyclohex‑2‑en‑1‑ylidene)oxalohydrazide (H4DOX). The geometry of isolated solid compounds was discussed by various spectroscopic methods. The optimized structures of complexes were confirmed by applying DFT theory. Also, the formation and association constants as well as Gibbs free energies of N′1,N′2‑bis(3‑hydroxy‑5,5‑dimethylcyclohex‑2‑en‑1‑ylidene)oxalohydrazide complexes were estimated at 298.15 K in a mixed solvent (DMSO‑EtOH). Moreover, biological activity was tested for all isolated compounds.
Journal Title: Journal of Molecular Liquids
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!