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The hydration behavior of d-glucose in the choline chloride: Urea:water mixtures

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Abstract The hydration behavior of d -glucose in aqueous solutions containing a deep eutectic solvent (DES) was studied in the temperature range: T = (293.15–313.15) K. For that, several volumetric, acoustic and… Click to show full abstract

Abstract The hydration behavior of d -glucose in aqueous solutions containing a deep eutectic solvent (DES) was studied in the temperature range: T = (293.15–313.15) K. For that, several volumetric, acoustic and viscometric properties were measured and calculated. The choline chloride + urea (1,2, molar ratio) eutectic mixture was chosen as co-solvent. The Hepler parameter and the viscosity B-coefficient showed that d -glucose in DES aqueous mixtures is a structure-making agent. Both the molar properties and the transfer properties suggested a strong solute-solvent interaction with predominance of the hydrophilic -hydrophilic contribution. Lastly, the calculated viscous flow activation parameters demonstrated high stability of the hydration structure.

Keywords: behavior glucose; chloride urea; choline chloride; hydration behavior

Journal Title: Journal of Molecular Liquids
Year Published: 2020

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