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Comments regarding “Solid-liquid equilibrium solubility, thermodynamic properties and solvent effect of 3,4-dinitro-1H-pyrazole in different pure solvents”

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Abstract A polemic is given regarding the thermodynamic mixing properties reported in the paper by Liu and coworkers. The authors' calculated thermodynamic mixing properties were found to be internally inconsistent,… Click to show full abstract

Abstract A polemic is given regarding the thermodynamic mixing properties reported in the paper by Liu and coworkers. The authors' calculated thermodynamic mixing properties were found to be internally inconsistent, and do not obey the standard thermodynamic relationship that ∆mixG = ∆mixH − T ∆mixS.

Keywords: equilibrium solubility; solid liquid; liquid equilibrium; solubility thermodynamic; regarding solid; comments regarding

Journal Title: Journal of Molecular Liquids
Year Published: 2020

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