Photo by martinadams from unsplash
Abstract Errors are discovered in the tabulated thermodynamic properties reported by Zhang and coworkers. The molar entropies of dissolution ΔsolS were wrong. The molar entropies do not to observe thermodynamic… Click to show full abstract
Abstract Errors are discovered in the tabulated thermodynamic properties reported by Zhang and coworkers. The molar entropies of dissolution ΔsolS were wrong. The molar entropies do not to observe thermodynamic law of S = −(∂G/∂T)P. In other words, the authors’ calculated thermodynamic properties were found to be internally inconsistent, and do not obey the standard thermodynamic relationship that ΔG = ΔH − TΔS.
Keywords:
comments thermodynamics;
solubility sulfamethazine;
sulfamethazine methanol;
methanol ethanol;
thermodynamics;
thermodynamics solubility
Journal Title: Journal of Molecular Liquids
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Journal of Molecular Liquids
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!