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Novel fluorescent sensor for silver (I) based on the 3,4-bis-triazole Bodipy via dual-click chemistry

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Abstract This investigation paper relates with a novel dual-Bodipy derivative obtained by using ‘click’ chemistry. The synthesized compounds were characterized by some techniques as 1 H NMR, 13 C NMR,… Click to show full abstract

Abstract This investigation paper relates with a novel dual-Bodipy derivative obtained by using ‘click’ chemistry. The synthesized compounds were characterized by some techniques as 1 H NMR, 13 C NMR, 11 B-NMR, 19 F NMR, FT-IR, Uv–vis, spectrofluorimetry, mass, elemental analysis, melting point. The photophysical measurements were conducted on 4,4-difluoro-8-(4-(3-{8-{3,4-Bis{1,2,3 triazolomethoxy}benzaldehyde)}propoxy))phenyl-4-bora-3a,4a, diaza-s-indacene ( Bodipy-T ) in presence of different metal ions. General trends were performed for emission, absorption, excitation, complex stoichiometry, different concentrations, competing ion, binding constants etc. in methanolic medium. Bodipy-T can be potentially served as a sensitive and selective ratiometric sensor for Ag (I) ion, moreover, it includes a modifiable group (aldehyde) for the preparing of its new derivatives.

Keywords: bodipy; nmr nmr; click chemistry; novel fluorescent; chemistry; sensor

Journal Title: Journal of Molecular Structure
Year Published: 2017

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