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Abstract A new proton-conductive Zn(II) coordination polymer, namely, [Zn(SDBA)(1,3-BMIB)·H 2 O] n ( 1 ) (1,3-BMIB = 1,3-bis(2-methyl-1-imidazolyl)benzene, H 2 SDBA = 4,4'-sulfonyldibenzoic acid)) has been synthesized under hydrothermal condition and characterized by elemental… Click to show full abstract
Abstract A new proton-conductive Zn(II) coordination polymer, namely, [Zn(SDBA)(1,3-BMIB)·H 2 O] n ( 1 ) (1,3-BMIB = 1,3-bis(2-methyl-1-imidazolyl)benzene, H 2 SDBA = 4,4'-sulfonyldibenzoic acid)) has been synthesized under hydrothermal condition and characterized by elemental analysis, and single-crystal X-ray diffraction. Single-crystal X-ray diffraction study reveals that complex 1 features 2D (4, 4) grid layer. Complex 1 exhibits strong fluorescent emissions in the solid state at room temperature. Moreover, complex 1 also exhibits a proton conductivity of over 10 −5 S cm −1 at 328 K and 99% relative humidity.
Journal Title: Journal of Molecular Structure
Year Published: 2017
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