Abstract In this study, peripherally and non-peripherally (2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy) substituted novel cobalt (II), manganese (III) phthalocyanines were synthesized by cyclotetramerization reaction of 4-(2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy)phthalonitrile and 3-(2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy)phthalonitrile. Also, electrochemical properties of peripheral and… Click to show full abstract
Abstract In this study, peripherally and non-peripherally (2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy) substituted novel cobalt (II), manganese (III) phthalocyanines were synthesized by cyclotetramerization reaction of 4-(2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy)phthalonitrile and 3-(2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy)phthalonitrile. Also, electrochemical properties of peripheral and non-peripheral tetra-(2-{2-[4-(1H-pyrrol-1-yl)phenoxy]ethoxy}ethoxy) group substituted cobalt (II), manganese (III) phthalocyanines were determined with cyclic (CV) and square wave (SWV) voltammetry techniques. According to the electrochemical results, cobalt (II), manganese (III) phthalocyanines give common reduction process, but they electropolymerized on the Pt working electrode during anodic potential scans.
Journal Title: Journal of Molecular Structure
Year Published: 2020
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