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Evidence of noncovalent interactions between sevoflurane and dimethyl ether. FTIR cryospectroscopic and ab initio studies

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Abstract The IR spectra of sevoflurane + dimethyl ether mixtures dissolved in liquid Kr are studied at T ∼118–155 K. The characteristic changes observed in numerous IR bands of both moieties suggest the… Click to show full abstract

Abstract The IR spectra of sevoflurane + dimethyl ether mixtures dissolved in liquid Kr are studied at T ∼118–155 K. The characteristic changes observed in numerous IR bands of both moieties suggest the formation of complexes stabilized by non covalent interactions of H-bond type. Estimations based on ab initio calculations including anharmonic effects are in line with the experimental findings.

Keywords: evidence noncovalent; dimethyl ether; sevoflurane dimethyl; noncovalent interactions

Journal Title: Journal of Molecular Structure
Year Published: 2020

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