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Large-scale synthesis of ZnO nanostructures by pulse electrochemical method and their photocatalytic properties

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Abstract In this paper, we report a simple environment-friendly and large-scale approach to synthesis of highly crystalline zinc oxide nanostructures using pulse alternating current (PAC). The morphological results demonstrate flower-like… Click to show full abstract

Abstract In this paper, we report a simple environment-friendly and large-scale approach to synthesis of highly crystalline zinc oxide nanostructures using pulse alternating current (PAC). The morphological results demonstrate flower-like architectures of nanoparticle-based and nanorod-based zinc oxide (ZnO-NPs and ZnO-NRs) obtained in KCl and NaCl as electrolytes. The photocatalytic activity of the obtained materials was performed in methylene blue dye degradation reaction under UV light irradiation. A high efficiency of ~ 90% within 60 min with excellent rate constant (k = 0.0386 min−1) was observed in the presence of ZnO-NPs synthesized in 2 M KCl which is attributed to the larger specific surface area (27 m2 g−1), total pore volume and more defective structure.

Keywords: large scale; scale synthesis; zno; zno nanostructures; synthesis zno

Journal Title: Materials Science in Semiconductor Processing
Year Published: 2018

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