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A direct charger transfer from interface to surface for the highly efficient spatial separation of electrons and holes: The construction of Ti–C bonded interfaces in TiO2-C composite as a touchstone for photocatalytic water splitting

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Abstract The construction of semiconductor composites is known a powerful method to realize the spatial separation of electrons and holes, which results in more electrons or holes dispersing on the… Click to show full abstract

Abstract The construction of semiconductor composites is known a powerful method to realize the spatial separation of electrons and holes, which results in more electrons or holes dispersing on the surface, accompanying a charge transfer and further extending the region of charge depletion at the interface between these two components of the composite. However, most of them are based on a random accumulation connection of two different crystals and there are obvious empty spaces, which are formed as deplete layer to hinders the charge transfer to a large extent. In order to shorten the charger transfer path and make a direct charge transform from interface to surface, a chemically bonded interface in the composite is more reasonable. In this work, using one-dimensional TiO 2 -C composite nanorods with a Ti–C chemically bonded interface as a touchstone, which was prepared through a simple carbonized process, the above strategy for better semiconductor photocatalytic water splitting property has been realized.

Keywords: spatial separation; charger transfer; surface; separation electrons; electrons holes; interface

Journal Title: Nano Energy
Year Published: 2017

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