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Graphene oxide-templated synthesis of ternary oxide nanosheets for high-performance Li-ion battery anodes

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Abstract Ternary oxide nanosheets are very promising Li-ion battery anode materials. However, they are challenging to synthesize due to their complex compositions. Current ternary oxide nanosheet synthesis strategies are limited… Click to show full abstract

Abstract Ternary oxide nanosheets are very promising Li-ion battery anode materials. However, they are challenging to synthesize due to their complex compositions. Current ternary oxide nanosheet synthesis strategies are limited and not scalable. Herein, a general methodology is presented for the synthesis of ternary oxide nanosheets with controlled compositions and properties, using graphene oxide as two-dimensional template. TiNb2O7 and Ti0.61Nb1.29O4 have been synthesized as nanosheets for the first time using the graphene oxide-templated method. In addition, NixCo3−xO4 and MnxCo3−xO4 nanosheets have been prepared with tunable compositions. The ternary oxide nanosheets were applied as Li-ion battery anodes with very promising performance.

Keywords: ion battery; graphene oxide; ternary oxide; oxide nanosheets

Journal Title: Nano Energy
Year Published: 2018

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