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Strong hydrogen bonding wide bandgap single crystal for optical and electronic applications

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Abstract The present work deals with an investigation on the synthesis, crystal growth and characterization of an organic molecule named, as 3-hydroxyanilinium p-Toluenesulfonate (3HAPTS) for third order nonlinear optical and… Click to show full abstract

Abstract The present work deals with an investigation on the synthesis, crystal growth and characterization of an organic molecule named, as 3-hydroxyanilinium p-Toluenesulfonate (3HAPTS) for third order nonlinear optical and electronic applications. A high quality of organic single crystal was grown by slow evaporation solution technique (SEST) and the characterization result reveals that the strong hydrogen bonding and interaction between the molecule. The FT-IR and NMR analyses were reveals that the confirmation of the functional group in the molecule. Thermal property of the material was investigated by Thermogravimetric analysis (TGA). The optical properties such as absorption and emission were studied through the UV–visible and fluorescence spectrophotometer. The wide bandgap energy of 3HAPTS calculated from the Kubelka-Munk function, and it was found to be 4.01 eV. The dielectric property, hardness and the mechanical behavior of the single crystal was done with Vicker’s microhardness test. The third order nonlinear optical behavior of 3HAPTS was analyzed by Z-scan analysis.

Keywords: electronic applications; single crystal; optical electronic; strong hydrogen; wide bandgap; hydrogen bonding

Journal Title: Optics and Laser Technology
Year Published: 2019

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