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Minimizing toxicity in bright green luminescent lead doped Mn-based microcrystals

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Abstract The perovskite nanoparticles got much attention in research due to their interesting optoelectronic properties. The true potential application of lead-based perovskite nanoparticle has been hampered due to its toxicity… Click to show full abstract

Abstract The perovskite nanoparticles got much attention in research due to their interesting optoelectronic properties. The true potential application of lead-based perovskite nanoparticle has been hampered due to its toxicity and stability. This paper demonstrated a green approach for toxicity removal of lead halide perovskites to resolve their toxicological aspects using manganese-based metal halide microcrystals. Pb doped Mn-based: CH3NH3Mn1-x PbxBr3-yCly microcrystals show better stability in solid-phase over solution phase with an absolute photoluminescent quantum yield [PLQY] of 30%. All characterization has been done using ultraviolet, photoluminescence, infrared spectra, X-ray photoelectron spectroscopy, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and thermogravimetric analysis.

Keywords: minimizing toxicity; microscopy; toxicity; doped based; toxicity bright; lead

Journal Title: Optical Materials
Year Published: 2020

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