Abstract The recently discovered Sanjiaowo Sn deposit is located in eastern Guangdong, SE China. The Sn mineralization, hosted in granite porphyry and the Lower Jurassic Jinji Formation low-grade metamorphic wall… Click to show full abstract
Abstract The recently discovered Sanjiaowo Sn deposit is located in eastern Guangdong, SE China. The Sn mineralization, hosted in granite porphyry and the Lower Jurassic Jinji Formation low-grade metamorphic wall rocks, is considered to be granite-related. Zircon U–Pb dating of the granite porphyry yielded concordant ages of 140.5 ± 1.4 Ma, which is consistent with the cassiterite U–Pb age of 139.8 ± 5.0 Ma, indicating a temporal link between the emplacement of granitic plutons and Sn mineralization. The granite porphyry samples are weakly peraluminous and show an A-type geochemical signature with high Na 2 O + K 2 O (7.19–8.51 wt.%), REE (261–308 ppm), Zr + Nb + Ce + Y (353–476 ppm) contents, FeO T /MgO (0.93–0.99), and Ga/Al (2.65–3.42) ratios. They display bulk rock initial 87 Sr/ 86 Sr of 0.7110 to 0.7165, eNd(t) of −5.90 to −4.04, and zircon eHf(t) values from −8.36 to −4.16 with Mesoproterozoic T DM2 ages for both Nd and Hf isotopes. Detailed elemental and isotopic data suggest that the Sanjiaowo Granite porphyry belongs to the A 2 -subtype and were formed by partial melting of a crustal source of Mesoproterozoic overall residence age with minor input of mantle materials. The low calculated zircon Ce 4+ /Ce 3+ (6.5–81.2) and Eu N /Eu N ∗ (0.05–0.24) ratios demonstrates that the Sanjiaowo granitic magma had a low oxygen fugacity, which may have facilitated the Sn enrichment and played a key role in the Sn mineralization. Lead isotopes indicate that there is no difference for 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, and 208 Pb/ 204 Pb ratios between the granite porphyry and the sulfide minerals from the orebodies. Moreover, the sulfur isotopic compositions for the sulfides (pyrite and pyrrhotite: δ 34 S = −1.6–1.0‰, average = −0.32) is similar to magmatic δ 34 S, but different from the δ 34 S in the Jinji Formation strata. Consequently, these data favor of a magmatic-hydrothermal origin for the Sn mineralization in the Sanjiaowo deposit. Integrating new and published data on the tectonic evolution, we suggest that the granite porphyry and associated Sn mineralization in the Sanjiaowo deposit formed in a back-arc extensional environment at ∼141 Ma, related to the rollback of the paleo-Pacific Plate.
               
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