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Fluid geochemistry of the Serra Pelada Au-Pd-Pt deposit, Carajás, Brazil: Exceptional metal enrichment caused by deep reaching hydrothermal oxidation

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Abstract Serra Pelada is a high-grade hydrothermal Au-Pd-Pt deposit within the Carajas mineral province, eastern Amazon craton, which shows an exceptional metal enrichment at carbon-enriched hosted ores (>1000’s ppm Au + Pt + Pd).… Click to show full abstract

Abstract Serra Pelada is a high-grade hydrothermal Au-Pd-Pt deposit within the Carajas mineral province, eastern Amazon craton, which shows an exceptional metal enrichment at carbon-enriched hosted ores (>1000’s ppm Au + Pt + Pd). The main orebody is structurally hosted at the hinge of a recumbent syncline, consisting of dolomitic metasandstones at the outer part of the fold, a layer of carbonaceous metasiltstone in which most orebodies are located, and red siltstone in the core of the fold. Distal hydrothermal alteration comprises spatially separated chlorite – carbon (reduced) and hematite (oxidized) alteration zones. The mineralized zones include silicification and argillic (carbon- kaolinite-, and hematite-rich) alteration zones. Fluid inclusions hosted by quartz and dolomite crystals from distal alteration zones and silicified portions within the mineralized zone record a wide range of salinity (5–22 wt% NaCleqv.) but relatively constant homogenization temperatures (170 ± 25 °C). Pressure and temperature estimations based in the fluid inclusion microthermometry and selenide thermometry constrain the formation of the deposit at 250–270 °C and 1.2–1.7 kbar. Element concentrations of alkali metals, Pb, Cs and to a lesser extent Ba correlate with salinity, whereas redox-sensitive elements including U and Ce vary widely. Gold concentrations from 50 to 500 ppb detected in some inclusions are consistent with the highly oxidizing conditions defined by selenide mineralogy. The presence of uranium and gold within fluid inclusions of the distal hematite alteration zone confirms the oxidizing, metal carrier fluids. The occurrence of hydrothermally precipitated carbon implies that a reducing CH4-bearing fluid was also present, and the structural relationships suggest that mixing between this reducing fluid (and interaction with carbon-upgraded rocks) with an acidic, oxidizing and metal-carrying fluids was the main process driving ore metal precipitation. The genesis of the Serra Pelada Au–Pd-Pt deposit shows similarities with sediment-hosted copper deposits and unconformity-related U ± Au ± PGE deposits, having in common the downflow of highly oxidizing fluids into the hydrothermal domain of the Earth's upper crust. Major differences in metal proportions of these broad classes of ore deposits and other sediment-hosted systems in different ore provinces are primarily caused by differences in source rocks available for oxidative leaching and variations in the geometry of the hydrothermal system.

Keywords: metal; geochemistry; deposit; alteration; serra pelada; carbon

Journal Title: Ore Geology Reviews
Year Published: 2019

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