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Genesis and tectonic setting of Shenshan Fe–Cu deposit in Inner Mongolia, Northeast China: Constraints from geochemistry, U–Pb and Re–Os geochronology, and Hf isotopes

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Abstract The newly-discovered Shenshan Fe–Cu skarn deposit is located in the southern Great Xing’an Range of northeastern China. The mineralization occurs mainly in the exoskarn or marble wallrocks of the… Click to show full abstract

Abstract The newly-discovered Shenshan Fe–Cu skarn deposit is located in the southern Great Xing’an Range of northeastern China. The mineralization occurs mainly in the exoskarn or marble wallrocks of the Permian Zhesi Formation, which were intruded by the Shenshan granodiorite and granite porphyry dykes. Molybdenite Re–Os dating yielded a weighted mean age of 160.2 ± 2.4 Ma (MSWD = 0.38), consistent with the LA–ICP–MS zircon U–Pb age of the granodiorite (161.6 ± 2.2 Ma; MSWD = 0.75), but significantly older than the granite porphyry dykes (132.8 ± 1.9 Ma; MSWD = 0.87). This suggests a coeval and causative relationship between the granodiorite and Fe–Cu mineralization. The Shenshan granodiorite has an adakite-like geochemical signature with high Sr contents (704–871 ppm), and high Sr/Y (46.79–80.21) and (La/Yb)N (17.54–31.13) ratios, but low Y (9.7–13.1 ppm) and Yb (0.70–1.18 ppm) contents. The granodiorite has relatively low contents of Mg (1.71–1.94 wt%), Cr (18–23 ppm), and Ni (4.1–9.0 ppm), and positive eHf(t) (−0.3 to 3.0, average 1.51), yielding two-stage model ages (TDM2) of 1.38–1.68 Ga (average 1.51 Ga). The results indicate that the parental magmas of the granodiorite were derived from partial melting of juvenile thickened lower crust with minor mantle-derived input. Meanwhile, the Shenshan granite porphyry dykes are high-K calc-alkalic and weakly peraluminous, with low MgO (0.21–0.24 wt%) and Mg# (19–21). The dykes exhibit HFSE (e.g., Nb, Ta) depletions and LILEs (e.g., Rb, K) enrichments, and strong to moderate negative Eu anomalies, indicating major continental crust-derived input in the magma source. Geochemical and Hf isotopic data compilation for granitoids across the Great Xing’an Range indicate that the mineralization at Shenshan was influenced by the south-dipping subduction of the Mongol–Okhotsk oceanic plate. The discovery of adakite-like rocks in the Shenshan Fe–Cu deposit, and the voluminous adakite-like rocks in the region, suggest that the Mesozoic Great Xing’an Range has considerable prospecting potential for Cu–Au–Mo deposits.

Keywords: geochronology; great xing; geochemistry; shenshan deposit; china

Journal Title: Ore Geology Reviews
Year Published: 2019

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