LAUSR

Abstract The molecular packing and optical properties of exposed and buried layers (i.e. the layers at the top surface and near the substrate, respectively) were systematically studied in 6,13-Bis(triisopropylsilylethynyl)pentacene (TIPS-pentacene) films coated by spin-coated (SC) and droplet-pinned-crystallization (DPC) methods. Buried layers in both films exhibit intense photoluminescence (PL) resembling the behaviors of the molecules in dilute solution ascribing to weak π-π stacking, while the exposed layers show extremely weak PL due to strong crystallinity. Polarized excitation PL spectra demonstrate that molecular orientation of the buried layers is quasi-ordered in the film coated by DPC method and completely disordered in the film coated by SC method. Besides, the strong crystallinity of the exposed TIPS-pentacene is verified by grazing incident wide-angle X-ray scattering measurement. The distinct differences in optical and structural properties between the exposed and buried layers indicate that TIPS-pentacene films are inhomogeneous in vertical direction due to interfacial effect, which affects the performance of photodiode fabricated with both films. The understanding of the molecular packing correlated fluorescence in TIPS-pentacene films is vital for optimizing the film structure to achieve high performance organic electronic devices.