Abstract Five sampling sites (Sites A, B, C, D and E) were selected along a 250 m sampling zone covered by Suaeda salsa , which is perpendicular to a road, in… Click to show full abstract
Abstract Five sampling sites (Sites A, B, C, D and E) were selected along a 250 m sampling zone covered by Suaeda salsa , which is perpendicular to a road, in the Yellow River Delta of China. Soil samples were collected to a depth of 40cm in these five sampling sites to investigate the profile distributions and toxic risks of heavy metals. Concentrations of heavy metals (As, Cd, Cr, Cu, Ni, Pb and Zn) were determined using inductively coupled plasma atomic absorption spectrometry (ICP-AAS). The results showed that in each sampling site, Cd, Cu, Pb and Zn have approximately constant concentrations along soil profiles and did not show high contamination compared with the values of probable effect levels (PELs). All soils exhibited As and Ni contamination at all sampling sites compared with other heavy metals. The index of geo-accumulation (I geo ) values for As in the 20–30 cm soil layer at Site B was grouped into Class Ⅳ(2 geo ≤ 3), indicating that the soil was moderately to strongly contaminated. Forty percent of I geo values of Cd for all soil samples were grouped into Class Ⅳ(2 geo ≤ 3) and 75% samples of Site C showed moderately to strongly contaminated level. The Enrichment factor (EF) values of As at Sites B, C, D and E reached significant enrichment level and EF values of Cd at five sampling sites all reached significant enrichment level. The sum of toxic units (∑TUs) values for surface soils of Sites B and C beyond 4 indicated that Sites B and C have severer toxicity compared with other three sampling sites. As and Ni should be paid more attention to avoid potential ecotoxicity due to their high contribution ratios to the ∑TUs in Suaeda salsa wetlands. Correlation analysis (CA) and principal components analysis (PCA) revealed that Cr, Cu, Ni, Pb and Zn might derive from the common sources, Cd might originate from another, while As might have more complex sources in this study area.
               
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