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C5–C13 light hydrocarbons of crude oils from northern Halahatang oilfield (Tarim Basin, NW China) characterized by comprehensive two-dimensional gas chromatography

Abstract The Halahatang Oilfield in the Tabei Uplift of the Tarim Basin has substantial petroleum potential and contains many prolific commercial oil reservoirs. In this study, a total of 15… Click to show full abstract

Abstract The Halahatang Oilfield in the Tabei Uplift of the Tarim Basin has substantial petroleum potential and contains many prolific commercial oil reservoirs. In this study, a total of 15 DST oils were sampled from the northern Halahatang oilfield, and their geochemistry of C 5 –C 13 light hydrocarbons (LHs) is characterized by two-dimensional gas chromatography (GC × GC). The concentrated clusters in the LH triangular diagrams and parent-daughter plots of the n -Heptane (%C 7 ) vs. ln (Cps/CHs) corroborating with the similar K 1 values (1.01–1.23), imply a high degree of compositional similarity and source affinity. The C 7 LHs show a predominance of n -heptane (30.07%–42.75%) and a nearly identical abundance of MCyC 6 (35.92%–45.85%), low I MCyC6 (methylcyclohexane index) value (35.92%–45.57%) and a moderate I CH (cyclohexane index) value (25.92%–45.66%), demonstrating that they were typical marine oils mainly originated from a substantial amount of sapropelic organic matter mixed with a nearly equivalent amount of humic one. The LH maturity indexes, such as the heptane (H) ratio (17.80%–29.28%), isoheptane (I) ratio (1.25–2.15), °C temp (113.72 °C −124.63 °C),methyladmantane index (MAI: 52.15%–63.65%) and equivalent vitrinite reflectance (1.1%–1.3% R o) indicate a high thermal maturity. The values of 3-ethyl-2-methylheptane to 3-methylnonane (MT 1 : 0.91–3.65), 1,1,2,3-tetramethylcyclohexane to propylcyclohexane (MT 2 : 0.85–1.37), 2-methyl-3-ethylheptane/2,6-dimethyloctane (MTR: 0.59–1.25), and Pr/Ph (0.87–1.62) observed for the northern Halahatang oils consistently suggest a marine carbonate lithology for the source rock deposited in an anoxic, reducing environment. Geochemical and geological correlation imply the Halahatang oils are possibly derived from the O 2+3 potential source rocks.

Keywords: light hydrocarbons; two dimensional; tarim basin; dimensional gas; northern halahatang; halahatang oilfield

Journal Title: Journal of Petroleum Science and Engineering
Year Published: 2017

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