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Abstract A hexanuclear complex of d10–d10 transition metal with organosulfur ligand, Ag6(py2t)6 (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray… Click to show full abstract
Abstract A hexanuclear complex of d10–d10 transition metal with organosulfur ligand, Ag6(py2t)6 (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag–Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex.
Journal Title: Polyhedron
Year Published: 2017
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