Abstract Two novel mononuclear heteroleptic Cu(I) complexes based on mixed phosphine/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. For both complexes, similar structural behavior was observed around Cu(I) atoms, which exhibited… Click to show full abstract
Abstract Two novel mononuclear heteroleptic Cu(I) complexes based on mixed phosphine/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. For both complexes, similar structural behavior was observed around Cu(I) atoms, which exhibited a distorted tetrahedral coordination geometry identified using τ4 parameter analysis. Interesting photophysical properties, including strong absorption in the UV–Vis spectral range (200–450 nm) and orange-red emission, were observed in the solid state upon excitation of the prepared compounds at λex = 290 nm. As shown by TD-DFT studies, the absorption and emission behavior of the Cu(I) complexes proved primarily related to HOMO and HOMO−1 to LUMO ((M+X)LCT Cu(d10) → π∗(S C N)) transitions. Complete characterization of the compounds also included X-ray studies, elemental analysis, IR spectroscopy, cyclic voltammetry, and absorption/emission investigation.
               
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