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Abstract Five ligands as monosubstituted derivatives of the basic skeleton of 2,6-bis(2-benzimidazyl)pyridine were synthesized, and characterized by NMR and IR spectra along with the X-ray structure analysis. Their complexation gave… Click to show full abstract
Abstract Five ligands as monosubstituted derivatives of the basic skeleton of 2,6-bis(2-benzimidazyl)pyridine were synthesized, and characterized by NMR and IR spectra along with the X-ray structure analysis. Their complexation gave a set of hexacoordinate Fe(II) complexes showing predominantly the diamagnetism until ambient temperature. Some temperature-independent paramagnetism along with an onset of the spin transition is also detected.
Keywords:
complexes formed;
pyridine;
low spin;
formed monosubstitued;
spin complexes;
spin
Journal Title: Polyhedron
Year Published: 2017
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Journal Title: Polyhedron
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!